The Keeling Curve

Ecosystems (Interaction and interdependence) · Transfers of energy and matter · note 8 of 9

The Keeling CurveSpec C4.2.20

In short

The Keeling Curve is the record of atmospheric carbon dioxide concentration measured at Mauna Loa, Hawaii, since 1958. Each year CO₂ falls in the northern summer, when photosynthesis exceeds respiration, and rises in winter, when respiration exceeds photosynthesis. The long-term rise, from about 315 ppm to over 420 ppm, is caused mainly by combustion of fossil fuels.

Measurements of CO₂ at the Mauna Loa Observatory, high on a volcano in Hawaii and far from local pollution, began in 1958. The graph shows two patterns.

PatternDescriptionExplanation
Annual fluctuationA saw-tooth of about 6 ppm each year: highest around May, lowest around September–OctoberMost land and vegetation is in the northern hemisphere. In the northern spring and summer, photosynthesis exceeds respiration, so CO₂ falls. In autumn and winter, leaves fall and photosynthesis slows while respiration (especially by decomposers) continues, so CO₂ rises
Long-term trendA steady rise, from about 315 ppm in 1958 to over 420 ppm in the 2020s, getting steeper over timeCombustion of fossil fuels (and deforestation) releases CO₂ faster than photosynthesis and the oceans remove it
The Keeling Curve: atmospheric CO₂ concentration at Mauna Loa in ppm from 1958 to 2025, rising from about 315 ppm to about 427 ppm along a line that gets steeper over time, with a regular yearly saw-tooth; an arrow along the trend is labelled long-term rise: combustion of fossil fuels. Below, one year (2020) is magnified month by month: a maximum in May (respiration greater than photosynthesis through the northern winter) and a minimum in September–October (photosynthesis greater than respiration through the northern summer). (opens full size in a new tab)
The Keeling Curve: a yearly cycle of about 6 ppm on top of a long-term rise. Drawn from NOAA Mauna Loa annual means with the average seasonal cycle; 2020 monthly values are approximate.
Exam tip:

When analysing the Keeling Curve, explain both patterns: the annual cycle in terms of photosynthesis and respiration, the long-term trend in terms of combustion. Quote values with units (ppm) and calculate a rate of increase where asked.

Exam tip:

Linking question: what are the direct and indirect consequences of rising carbon dioxide levels in the atmosphere? Link to the enhanced greenhouse effect (D4.3) and ocean acidification.

Written and checked against the IB Biology HL specification · Updated October 2026

Frequently asked questions

Why is energy lost between trophic levels?

Energy is lost between trophic levels because not all of an organism is eaten, not all food eaten is digested, and much of the absorbed energy is converted to heat in cell respiration. Heat is lost to the environment. Typically only about 10% of the energy passes to the next level, which limits food chain length.

What is the difference between an autotroph and a heterotroph?

An autotroph uses an external energy source, light or oxidation reactions, to synthesise carbon compounds from simple inorganic substances such as carbon dioxide. A heterotroph uses carbon compounds obtained from other organisms, digesting and assimilating them to build the carbon compounds it needs. Both release energy by cell respiration.

Why can matter be recycled in ecosystems but energy cannot?

Matter is recycled because atoms are conserved: decomposers break down dead organic matter and release elements in inorganic forms that producers reuse. Energy cannot be recycled because it is eventually converted to heat by cell respiration, and organisms cannot convert heat back into chemical energy. New energy must keep arriving as sunlight.

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